you can put the stock valves on a 4.8, 5.3 but you will have to mill the heads .050 and then mill the intake side of the the heads to match your intake manifold, if you plan on using larger valves then no they wont work, just ask me how i know this lol (have some 2.02 1.57 ls1 heads) sitting on the living room floor collecting dust lol
If it was me i would keep the stock heads and have them milled .020 and use 7.35 push rods and run 2.02 1.57 valves in it.